Want to change your username on Facebook? This guide will show you how to do it. [Note: keep in mind that you can change your username only once.]
Once you have logged in to Facebook, click on the small triangle at the top right hand corner of the page and then select the option that says “Settings.”
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Once you have done that, click on the “Edit” link at the right extreme of the “Username” section.
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Finally, in the appearing form, enter your new username and then click on the "Save Changes" button.
This way you will change your username on Facebook.